5+ Excel Organizational Chart Templates. An organizational chart is a visual representation of the hierarchical structure of an organization. It shows relationships between different functions and roles, brings clarity about who reports to whom, and shows the chain of command. Update and customize this template using the Excel SmartArt feature. Select the chart then go to the SmartArt Tools tab to edit the Design and Formatting. To add photos, click on the placeholder image icons and the Insert Pictures window will open up automatically, then choose the image you want to use. Use this template to show the structure of a company, division, team, or other group, a view of who reports to whom, the title for each position, and the name of the person currently in each role. Download Hierarchical Organization Chart Template - Excel